This Battery Material Literally Breathes While Charging & Could Make Lithium-Ion Batteries Last Longer
Silicon has long been viewed as one of the most promising materials for building the next generation of lithium-ion batteries. It can store far more lithium than the graphite used in most commercial battery anodes, potentially allowing batteries to hold much more energy without dramatically increasing their size. But silicon has a major weakness: it expands and contracts dramatically every time a battery is charged and discharged . This repeated movement can damage the material, break electrical connections and destabilize the protective layer around the electrode. Eventually, the battery loses capacity and performance. Now, researchers led by Qiangfeng Xiao have developed a new type of silicon structure designed to solve this problem. Their hierarchically porous silicon nanospheres (hp-SiNSs) contain both a porous outer shell and a hollow interior. Instead of expanding outward like conventional silicon particles, these structures can accommodate lithium by expanding mainly inward . ...